Polic Chemical

Knowledge

Material Safety Data Sheet: Allyl Phenoxy Acetate

Identification

Product Name: Allyl Phenoxy Acetate
Synonyms: 2-Propenyl 2-Phenoxyacetate
Chemical Formula: C11H12O3
CAS Number: 7493-74-5
Recommended Use: Fragrance ingredient, chemical intermediate
Supplier Details: Contact manufacturer or supplier for specific details
Emergency Phone: Available from supplier's emergency response program
Molecular Weight: 192.21 g/mol

Hazard Identification

Classification: Irritant to eyes, skin, and respiratory system
Label Elements: Signal word: Warning; Hazard pictograms: Exclamation Mark
Hazard Statements: Causes skin and eye irritation, may cause respiratory irritation, harmful if swallowed
Precautionary Statements: Avoid breathing vapors, use outdoors or in a well-ventilated area, wear protective gloves, wash skin thoroughly after handling, avoid release to the environment
Routes of Exposure: Inhalation, dermal contact, ingestion

Composition / Information on Ingredients

Chemical Name: Allyl Phenoxy Acetate
Concentration: 98% or higher
Impurities: Trace amounts of phenol derivatives and allyl compounds
Additives: None reported
Stabilizers: None reported

First Aid Measures

Eye Contact: Rinse thoroughly with plenty of water for at least 15 minutes, remove contact lenses if present and easy to do, seek medical attention if irritation persists
Skin Contact: Remove contaminated clothing, wash affected area with soap and water, seek medical advice if irritation develops
Inhalation: Move individual to fresh air, provide oxygen if breathing is difficult, seek medical attention if symptoms persist
Ingestion: Do not induce vomiting, rinse mouth with water, get medical help immediately

Fire-Fighting Measures

Flammability: Combustible liquid
Suitable Extinguishing Media: Dry chemical, carbon dioxide, foam, water spray
Unsuitable Extinguishing Media: High pressure water streams may spread fire
Hazardous Combustion Products: Carbon monoxide, carbon dioxide, irritating fumes
Protective Equipment for Firefighters: Self-contained breathing apparatus and full protective clothing

Accidental Release Measures

Personal Precautions: Evacuate unnecessary personnel, follow proper ventilation protocols, avoid inhaling vapors
Protective Equipment: Chemical-resistant gloves, safety goggles, protective clothing
Environmental Precautions: Prevent release to soil, ditches, sewers, and waterways, notify emergency personnel if significant quantities are released
Cleanup Methods: Absorb spill with non-combustible material such as sand or earth, place in container for proper disposal, ventilate area and wash spill site after material pickup is complete

Handling and Storage

Handling: Avoid contact with skin, eyes, and clothing, keep containers tightly closed, use with adequate ventilation, do not breathe vapors, wear personal protective equipment
Storage: Store in a cool, dry, well-ventilated area, keep away from heat, sparks, and open flames, store in original container, keep away from incompatible substances such as strong oxidizers, acids, and bases, secure area to prevent unauthorized access

Exposure Controls and Personal Protection

Occupational Exposure Limits: No established TLV or PEL for allyl phenoxy acetate
Engineering Controls: Local exhaust or general dilution ventilation
Personal Protective Equipment: Chemical splash goggles, gloves (nitrile or neoprene), laboratory coat or coveralls, use approved respirator if airborne concentration is excessive
General Hygiene Measures: Wash hands and face after handling, avoid food and drinks in work area, maintain eyewash station and safety shower nearby

Physical and Chemical Properties

Appearance: Clear colorless to pale yellow liquid
Odor: Sweet, floral
Boiling Point: 135-145°C at 0.5 mmHg
Melting Point: Not applicable (liquid at room temperature)
Flash Point: 120°C (closed cup)
Vapor Pressure: 0.01 mmHg at 25°C
Solubility in Water: Slightly soluble
Density: 1.13 g/cm³ at 20°C
Viscosity: Not available

Stability and Reactivity

Chemical Stability: Stable under normal storage and handling conditions
Possibility of Hazardous Reactions: Avoid exposure to heat, open flames, strong acids, strong bases, and strong oxidizing agents
Decomposition Products: Carbon monoxide, carbon dioxide, phenolic compounds
Conditions to Avoid: Heat, sparks, static discharge, direct sunlight
Incompatible Materials: Strong oxidizers, acids, bases

Toxicological Information

Acute Toxicity: Expected to have moderate toxicity based on structural similarity to related compounds
Routes of Exposure: Skin, eyes, inhalation, ingestion
Symptoms of Exposure: Irritation of skin, eyes, and respiratory tract, nausea, headache
Chronic Effects: Prolonged or repeated exposure may cause dermal sensitization
Carcinogenicity: Not classified as a carcinogen by IARC, NTP, or OSHA
Other Effects: No evidence of mutagenic or reproductive toxicity from available data

Ecological Information

Ecotoxicity: Potentially harmful to aquatic life in concentrated spills;
Persistence and Degradability: Expected to be biodegradable over time though may persist initially
Bioaccumulation Potential: Moderate, based on estimated partition coefficient
Mobility in Soil: Limited mobility due to moderate solubility
Other Adverse Effects: Avoid uncontrolled release to environment as effects on beneficial organisms are not fully known

Disposal Considerations

Waste Disposal: Use approved chemical waste incineration or disposal method through licensed service
Container Disposal: Triple rinse, destroy or recycle per local regulations
Additional Recommendations: Do not dump into drains, surface water, or soil, comply with all federal and local environmental protection regulations

Transport Information

UN Number: Not regulated under most international regulations
Proper Shipping Name: Chemical, N.O.S. (Not Otherwise Specified)
Transport Hazard Class: Non-hazardous for transport
Packaging Requirements: Keep tightly sealed in chemical-safe packaging, protected from physical damage and clear labeling
Special Precautions: Emergency procedures recommended if leaks or spills occur during transport

Regulatory Information

Inventory Status: Listed or exempt on TSCA, EINECS, DSL/NDSL
SARA Title III Sections 311/312: Immediate health hazard
California Proposition 65: Not listed as a known carcinogen or reproductive toxicant
Other Regulations: Subject to workplace control and hazard communication standards as per OSHA and EU REACH regulations
Labeling Requirements: Ensure workplace labeling follows GHS rules, keep updated SDS at point of use