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Material Safety Data Sheet: Aminoethylethanolamine (AEEA)

Identification

Product Name: Aminoethylethanolamine
Synonyms: 2-(2-Aminoethylamino)ethanol, AEEA
CAS Number: 111-41-1
Recommended Use: Industrial chemical, surfactant, corrosion inhibitor, chelating agent
Manufacturer/Supplier: Listed on original shipping label
Phone for Emergency: Refer to local poison control/emergency medical services

Hazard Identification

Classification (GHS): Acute Toxicity (Category 4, oral, dermal), Skin Corrosion/Irritation (Category 1C), Eye Damage/Irritation (Category 1)
Signal Word: Danger
Hazard Statements: Harmful if swallowed or in contact with skin, causes severe skin burns and eye damage, can irritate respiratory tract
Pictograms: Corrosion, Exclamation mark
Precautionary Statements: Avoid breathing vapors, wash skin thoroughly, wear protective clothing and eye protection, do not eat/drink/smoke while using
Potential Health Effects: Causes deep burns, irritates airways, dangerous to eyes, ingestion could damage intestinal tract

Composition / Information on Ingredients

Chemical Name: Aminoethylethanolamine
CAS Number: 111-41-1
Concentration: 99% or higher (Pure substance)
Impurities/Stabilizers: Typical commercial product contains trace process residuals, not significant at listed concentrations

First Aid Measures

Inhalation: Remove person to fresh air, keep at rest, provide oxygen if breathing is difficult, seek medical attention
Skin Contact: Remove contaminated clothing, flush with running water for at least 15 minutes, obtain medical advice quickly
Eye Contact: Rinse thoroughly with running water for at least 15 minutes, lifting eyelids, get immediate medical help
Ingestion: Do not induce vomiting, rinse mouth, give water if conscious, seek immediate care
Most Important Symptoms: Burning pain, blisters, redness, visual impairment, shortness of breath

Fire-Fighting Measures

Suitable Extinguishing Media: Water spray, dry chemical, carbon dioxide, foam
Specific Hazards: Produces toxic fumes of nitrogen oxides, carbon monoxide, carbon dioxide during fire
Special Protective Equipment: Wear self-contained breathing apparatus, full protective suit, avoid direct contact with product or smoke
Fire Fighting Precautions: Remove all people from area, stay upwind, cool containers with water
Explosion Hazard: Not classified as flammable but may intensify fire if heated

Accidental Release Measures

Personal Precautions: Wear eye protection, chemically-resistant gloves, avoid breathing vapors
Environmental Precautions: Prevent entry into waterways, drains, or soil
Spill Response: Ventilate area, absorb with inert material (sand, earth), collect in labeled containers, clean residue with water
Decontamination: Wash area thoroughly with large quantities of water
Disposal: Follow disposal section for all contaminated items and cleanup material

Handling and Storage

Handling: Keep container tightly closed, work in well-ventilated areas, avoid breathing fumes or direct skin/eye contact, use personal protective equipment suited for corrosive substances
Storage: Store in original container, protected from moisture and strong acids, keep below recommended storage temperature (generally under 30°C), store in a dry, well-ventilated place away from heat sources, incompatible with oxidizers and strong acids
Special Storage Needs: Keep away from food, beverages, and animal feed, use secondary containment to manage leaks

Exposure Controls and Personal Protection

Exposure Limits: No established OSHA PEL or ACGIH TLV for AEEA; minimize exposure
Engineering Controls: Use fume hoods, adequate general ventilation, and local exhaust at points of vapor generation
Personal Protective Equipment: Chemical splash goggles, face shield, impervious gloves (nitrile, neoprene), long-sleeved clothing, chemical-resistant shoes
Respiratory Protection: Use respirators with organic vapor/acid gas cartridges if ventilation is not enough
Workplace Hygiene: Remove and wash contaminated clothing, practice good skin hygiene, never eat/drink/smoke around chemicals

Physical and Chemical Properties

Appearance: Clear to pale yellow liquid
Odor: Ammonia-like, unpleasant
pH: Approximately 11 (highly alkaline)
Melting Point: –34°C
Boiling Point: 243°C
Flash Point: 125°C (closed cup)
Evaporation Rate: Slow
Solubility: Miscible in water, hygroscopic
Vapor Pressure: Low at ambient temperature
Vapor Density: Heavier than air
Relative Density: Around 1.03 g/cm³
Viscosity: Moderate
Stability: Stable under normal storage, sensitive to oxidizers

Stability and Reactivity

Chemical Stability: Stable under recommended conditions, reacts with oxidizers and strong acids
Conditions to Avoid: Exposure to air for long periods, excess heat, acid vapors
Incompatible Materials: Oxidizing agents, acid chlorides, acid anhydrides, mineral acids
Hazardous Decomposition: Nitrogen oxides, carbon monoxide, ammonia, small amounts of amines
Polymerization: Product does not polymerize

Toxicological Information

Acute Toxicity: Harmful if swallowed (oral LD50 in rats approximately 1,480 mg/kg), also harmful via skin contact (dermal LD50 around 2,500 mg/kg, rat)
Skin Corrosion/Irritation: Causes deep burns, blisters on exposure
Eye Damage/Irritation: Severe eye damage likely rapidly on contact
Respiratory Irritation: Causes coughing, sore throat, difficulty breathing
Chronic Effects: Repeated or prolonged skin exposure may cause dermatitis, asthma implications not fully studied
Sensitization: Not classified as sensitizer, but rare cases may occur
Carcinogenicity: Not listed by IARC, NTP, OSHA
Mutagenicity and Reproductive: Limited data suggest no significant risks at industrial exposure levels

Ecological Information

Aquatic Toxicity: Toxic to aquatic life at high concentrations (LC50 fish, 24-96 hr: 90-100 mg/L); can raise pH in water bodies
Persistence and Degradability: Readily biodegradable under aerobic conditions
Bioaccumulation: Not expected to bioaccumulate, low octanol-water partition coefficient
Mobility in Soil: Moves freely in soil, but binds to organics
Other Effects: Spills can disrupt wastewater treatment and local ecosystems

Disposal Considerations

Waste Disposal: Handle as hazardous waste, incinerate liquid residues in licensed facilities, neutralize small spills with dilute acid then rinse with water
Container Disposal: Triple rinse containers, do not reuse, send to chemical waste disposal site
Other Disposal Notes: Observe all local, regional, and national regulations for chemical disposal, do not allow product to reach sewer or soil

Transport Information

UN Number: UN 2672
Proper Shipping Name: Aminoethylethanolamine
Transport Hazard Class: 8 (Corrosive substances)
Packing Group: III
Marine Pollutant: No
Other Transport Notes: Ensure secure packing, avoid overfilling, verify labeling matches content

Regulatory Information

OSHA Classification: Hazardous, regulated under OSHA Hazard Communication Standard
TSCA Status: Listed on US TSCA Inventory
SARA 313: Not subject to reporting
REACH Status: Registered in the EU
State Ingredients Disclosure: May be regulated in some US states for occupational and environmental releases
WHMIS Classification: D2B Toxic, E Corrosive (Canada)
Other Notes: Check regional requirements for worker protection and release reporting