Polic Chemical

Knowledge

Material Safety Data Sheet (MSDS) for Dipropylamine (DPA)

1. Identification

Product Name: Dipropylamine
Synonyms: N-Propylpropan-1-amine
Chemical Formula: C6H15N
CAS Number: 142-84-7
Recommended Use: Intermediates in chemical synthesis, corrosion inhibitors, agricultural chemicals
Manufacturer/Supplier: Ensure the details provided are specific to your source
Emergency Phone Number: Refer to your local regulations and supplier information for regional numbers

2. Hazard Identification

Classification: Flammable liquid (Category 3), Acute toxicity - oral and dermal (Category 4), Skin corrosion/irritation (Category 2), Eye irritation (Category 2A), Specific target organ toxicity - single exposure (Category 3, narcotic effects)
Signal Word: Warning
Hazard Statements: Flammable liquid and vapor. Harmful if swallowed, in contact with skin, or if inhaled. Causes skin and eye irritation. May cause respiratory irritation.
Pictograms: Flame, Exclamation mark
Precautionary Statements: Keep away from ignition sources. Avoid breathing mist or vapor. Do not eat, drink, or smoke while using this product. Wash skin thoroughly after handling. Wear protective gloves, clothing, and eye protection.

3. Composition / Information on Ingredients

Chemical Name: Dipropylamine
Concentration: ≥99%
CAS Number: 142-84-7
Impurities: Minor amounts of secondary or mixed amines possible; check certificate of analysis for lot specifics
Other Identifiers: EC number 205-553-3

4. First Aid Measures

Eye Contact: Rinse carefully with water for at least 15 minutes. Remove contact lenses if present and easy to do. Monitor for signs of irritation, seek medical advice right away.
Skin Contact: Remove contaminated clothing, rinse skin with soap and water for at least 15 minutes. If irritation develops or persists, get medical attention.
Inhalation: Move victim to fresh air. Support breathing as needed. Seek immediate medical attention for any signs of respiratory distress.
Ingestion: Rinse mouth thoroughly with water. Do not induce vomiting unless advised by medical personnel. Get medical help quickly.
Most Important Symptoms: Burning, irritation of eyes and mucous membranes, drowsiness, nausea, headache, dizziness
Advice for Rescuers: Use appropriate personal protective equipment. Do not leave affected individuals unattended.

5. Fire-Fighting Measures

Suitable Extinguishing Media: Dry chemical, alcohol-resistant foam, carbon dioxide, water spray (do not use a direct water jet)
Specific Hazards: Forms flammable mixtures with air. Thermal decomposition produces toxic vapors including oxides of nitrogen and carbon monoxide.
Special Protective Equipment for Firefighters: Self-contained breathing apparatus (SCBA) and full protective gear
Firefighting Instructions: Evacuate area. Cool containers exposed to fire with water spray. Take action from a safe distance.
Explosion Risk: Vapors can travel to ignition source and flash back. Containers may rupture under heat.

6. Accidental Release Measures

Personal Precautions: Wear gloves, safety goggles, and respirator. Remove all ignition sources. Ventilate area.
Environmental Precautions: Prevent leakage into drains, watercourses, or soil. Notify authorities if major spill contaminates environment.
Containment Methods: Dike and contain spill with inert material (sand, earth).
Clean-Up Procedures: Collect with non-sparking tools. Absorb with appropriate inert material. Transfer to labeled waste containers for disposal.
Additional Notes: Wash area with water after removal. Check local regulations for approved disposal methods.

7. Handling and Storage

Handling: Avoid breathing vapors. Avoid contact with skin and eyes. Use only in well-ventilated spaces. Ground and bond containers when transferring.
Storage: Store in tightly closed containers in a cool, dry, well-ventilated area. Keep away from heat, open flame, and incompatible materials.
Incompatible Materials: Strong acids, strong oxidizers, halogens
Storage Class: Flammable liquids. Keep away from substances that may react violently
Special Provisions: Store away from food or feed. Maintain proper labeling on containers.

8. Exposure Controls and Personal Protection

Occupational Exposure Limits: Check national regulations. ACGIH TLV (TWA): 5 ppm
Engineering Controls: Mechanical exhaust ventilation, local fume extraction, explosion-proof equipment
Personal Protective Equipment: Nitrile gloves, chemical splash goggles, flame-resistant clothing, suitable respirator (NIOSH approved for organic vapor, as needed)
Hygiene Measures: Wash hands after use, take off contaminated clothing, launder before reuse.
Environmental Controls: Prevent vapor and spillage from reaching sewers, waterways, or soil.

9. Physical and Chemical Properties

Appearance: Clear, colorless to pale yellow liquid
Odor: Amine-like, strong
Boiling Point: 110 °C (230 °F)
Melting Point: -36 °C (-32.8 °F)
Flash Point: 28 °C (82 °F) (closed cup)
Flammability: Highly flammable liquid and vapor
Explosion Limits: Lower: 1.3% v/v; Upper: 8.6% v/v
Vapor Pressure: Approx. 34 mmHg at 20°C
Solubility: Slightly soluble in water, miscible with most organic solvents
Density: 0.735 g/cm³ at 20°C
pH Value: Alkaline; forms basic solution
Partition Coefficient (n-octanol/water): log Kow = 1.34

10. Stability and Reactivity

Chemical Stability: Stable under recommended storage and handling conditions
Conditions to Avoid: Heat, flames, sparks, strong oxidizing conditions, incompatible substances
Incompatible Materials: Acids, oxidizers, halogens, nitric acid, peroxides
Hazardous Decomposition Products: Nitrogen oxides, carbon oxides, ammonia, toxic vapors
Hazardous Polymerization: Will not occur under normal conditions

11. Toxicological Information

Routes of Exposure: Inhalation, ingestion, skin contact, eye contact
Acute Toxicity: LD50 (oral, rat): 820 mg/kg; LD50 (dermal, rabbit): >2000 mg/kg
Chronic Effects: Prolonged exposure may affect liver, kidneys, and nervous system
Skin/Eye Irritation: Causes moderate to severe irritation
Respiratory Sensitization: Possible irritation, coughing, difficulty breathing
Carcinogenicity: Not listed as carcinogen by IARC, NTP, OSHA
Mutagenicity: Data insufficient in public literature
Reproductive Toxicity: Not identified

12. Ecological Information

Ecotoxicity: Harmful to aquatic life. LC50 (96hr, Fish): 46.7 mg/L
Persistence and Degradability: Expected to degrade in the environment by oxidation and biological processes
Bioaccumulation: Low potential, log Kow low
Mobility in Soil: Mobile in soils, may leach to groundwater in large spills
Other Adverse Effects: Avoid release to the environment. Do not allow product or rinse water to enter surface waters, sewers, or soil untreated.

13. Disposal Considerations

Waste Disposal Methods: Incinerate at approved facility or dispose according to local, national, and regional regulations
Empty Container Handling: Rinse thoroughly before discarding. Do not cut or weld containers that contained this product.
Environmental Cautions: Do not discharge into drains, surface water, or soil
Disposal of Spilled Product: Collect all waste and residues safely for approved disposal; consult authorities for large quantities or contaminated materials

14. Transport Information

UN Number: UN 2383
Proper Shipping Name: Dipropylamine
Hazard Class: 3 (Flammable Liquids)
Packing Group: II
Labels Required: Flammable liquid
Environmental Hazards: Check with authorities and shipping company for any special environmental transport rules
Special Precautions: Provide ventilation, keep away from heat and static, secure containers during transportation

15. Regulatory Information

TSCA Status: Listed on the Toxic Substances Control Act (TSCA) Inventory
REACH Status: Registered under European Union regulations
OSHA Hazards: Flammable liquid, hazardous substance
SARA Title III: Section 313 (Toxic Chemical Release Reporting) – Not listed
Canadian WHMIS Classification: B2 (Flammable Liquid), D2B (Toxic)
GHS Classification: Flammable Liquid Category 3, Acute Toxicity Category 4, Skin Irritation Category 2
Other Regulations: Product labeling and handling must comply with current local, state, and federal safety requirements.