Product Name: Octylamine
Chemical Formula: C8H19N
Synonyms: 1-Octanamine, n-Octylamine
CAS Number: 111-86-4
Recommended Uses: Intermediate for organic synthesis, corrosion inhibitors, flotation agents, rubber accelerators, dyes, pharmaceuticals
Supplier Details: Manufacturer or distributor address and emergency contact details included with shipment
Emergency Phone: Refer to label or reach local poison center
UN Number: UN 2734
GHS Classification: Acute toxicity (oral, dermal), skin corrosion/irritation, aquatic toxicity
Signal Word: Danger
Hazard Statements: Causes severe skin burns and eye damage, toxic if swallowed, harmful in contact with skin, very toxic to aquatic life
Pictograms: Corrosive, Skull and crossbones, Environmental hazard
Precautionary Statements: Do not breathe dust/fumes/gas/mist/vapors/spray, wear protective gloves and eye/face protection, avoid release to environment
Routes of Entry: Inhalation, skin and eye contact, ingestion
Target Organs: Skin, eyes, gastrointestinal tract, respiratory system
Chemical Name: Octylamine
CAS Number: 111-86-4
Concentration: ≥ 98% (for pure material)
Impurities: Trace amounts of related alkylamines
Additives: None expected in standard grade
Inhalation: Remove to fresh air, keep at rest, seek medical attention if symptoms occur
Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes, remove contaminated clothing, obtain medical attention
Eye Contact: Rinse cautiously with water for several minutes, remove contact lenses if present, continue rinsing and get immediate medical help
Ingestion: Rinse mouth, do not induce vomiting, seek medical attention immediately
Most Important Symptoms: Burning sensation, redness, pain, blisters, possible delayed effects such as ulceration or scarring
Notes for Physician: Treat symptomatically, monitor for respiratory distress, possible delayed pulmonary effects
Suitable Extinguishing Media: Carbon dioxide, dry chemical powder, foam, water spray for large fires
Unsuitable Media: Jets of water may scatter and spread fire
Hazards from Combustion: Emits toxic fumes under fire conditions such as nitrogen oxides, carbon monoxide, ammonia
Protective Equipment for Firefighters: Full protective suit with self-contained breathing apparatus
Specific Methods: Move containers from fire area if safe, prevent fire-fighting water from entering drains or waterways
Explosion Data: Vapors may form explosive mixtures with air, has flammability limits
Personal Precautions: Evacuate unnecessary personnel, ventilate area, wear chemical-resistant gloves, goggles, and face protection
Environmental Precautions: Prevent from entering sewers or waterways, inform relevant authorities if contamination occurs
Methods for Cleaning Up: Absorb with inert material such as sand or earth, scoop into labeled drums, dispose according to regulations, ventilate affected area
Spill Containment: Use containment booms for large spills, avoid dust or vapor formation during cleanup
Decontamination: Wash area with plenty of water after pickup
Precautions for Safe Handling: Work in well-ventilated area, avoid inhalation and contact, use only non-sparking tools, handle only in closed systems
Advice on General Occupational Hygiene: No eating, drinking or smoking in handling area, wash hands thoroughly after handling
Storage Requirements: Store in cool, dry, well-ventilated place, keep container tightly closed and locked up, segregate from oxidizers, acids, and foodstuffs
Container Materials: Suitable containers include stainless steel, HDPE, avoid contact with copper, brass, aluminum containers
Occupational Exposure Limits: No established OSHA or ACGIH limits, minimize exposure by effective engineering controls
Engineering Controls: Local exhaust ventilation, safety showers and eyewash facilities near handling areas
Personal Protective Equipment: Chemical-resistant gloves (nitrile or neoprene), flame-resistant lab coat, goggles or face shield, respirator for high concentrations
Respiratory Protection: Use organic vapor/acid gas cartridge respirators if ventilation is inadequate
Hand Protection: Impermeable gloves
Eye/Face Protection: Safety goggles with side shields and face shield for splash risk
Skin Protection: Chemical-resistant protective clothing, boots
Hygiene Measures: Shower after handling, launder clothing before reuse
Appearance: Colorless to pale yellow liquid
Odor: Ammoniacal, fishy
Odor Threshold: Not available
pH: Alkaline, can cause burns
Melting Point: -12°C
Boiling Point: 176°C
Flash Point: 63°C (closed cup)
Flammability: Flammable liquid and vapor
Explosive Limits: Lower 1.1%, Upper 7.9% (v/v in air)
Vapor Pressure: 0.49 kPa at 20°C
Vapor Density: 4.5 (air = 1)
Relative Density: 0.78 at 20°C
Solubility: Moderately soluble in water, miscible with ethanol, ether, chloroform
Partition Coefficient (log Kow): 2.6
Auto-Ignition Temperature: 235°C
Decomposition Temperature: Not determined
Viscosity: Low, comparable to kerosene
Chemical Stability: Stable in normal conditions
Conditions to Avoid: Heat, sparks, open flames, static discharge, incompatible materials
Incompatible Materials: Strong oxidizing agents, acids, copper, brass, aluminum, halogens
Hazardous Decomposition Products: Nitrogen oxides, ammonia, carbon monoxide and dioxide
Possibility of Hazardous Reactions: Violent polymerization or exothermic reactions with strong acids or oxidizers
Acute Toxicity: Oral LD50 (rat): 612 mg/kg, Dermal LD50 (rabbit): 1,420 mg/kg
Inhalation: Harmful, may cause respiratory distress, coughing, shortness of breath
Skin Corrosion/Irritation: Causes severe irritation or burns
Serious Eye Damage/Irritation: Causes serious eye damage
Respiratory or Skin Sensitization: May cause allergic reaction in susceptible individuals
Chronic Effects: Prolonged exposure leads to dermatitis, possible liver and kidney injury
Mutagenicity: No data
Carcinogenicity: Not listed by IARC, NTP, OSHA
Reproductive Toxicity: No reliable studies
Symptomatology: Irritation, headache, nausea, burns, possible systemic toxicity
Toxicity: Highly toxic to aquatic organisms, LC50 (Fish, 96 hr): 5.3 mg/L
Persistence and Degradability: Expected to be readily biodegradable
Bioaccumulation Potential: Moderate potential, log Kow above 2
Mobility in Soil: Moderate to high volatility, potential for leaching
Other Adverse Effects: Formation of persistent toxic mixtures in water, avoid direct discharge
Environmental Precautions: Prevent large losses to soils and water bodies, notify authorities in case of significant spill
Waste Disposal Methods: Dispose of contents/container through an authorized hazardous waste collection point
Contaminated Packaging: Triple rinse, remove labels, send to chemical waste handler
Special Precautions: Do not discharge to sewers or surface waters, prevent leaks or spills during transfer
Regulations: Follow local, regional, and national regulations; EPA and RCRA guidelines apply in the United States
UN Number: UN 2734
UN Proper Shipping Name: Amines, liquid, corrosive, flammable, n.o.s. (Octylamine)
Transport Hazard Class(es): 3 (Flammable liquid), 8 (Corrosive liquid)
Packing Group: II
Labels: Flammable liquid, Corrosive
Marine Pollutant: Yes
Special Precautions: Handle in accordance with good industrial hygiene and safety practices during transportation, keep away from incompatible chemicals
TSCA Status: Listed on the TSCA inventory
SARA Title III: Not listed as extremely hazardous, not subject to reporting under Section 313
EU Regulation: Classified as dangerous under Regulation (EC) No 1272/2008 (CLP)
WHMIS (Canada): Class B2 Flammable, Class E Corrosive, Class D2B Toxic material
Other Regulations: Compliant with REACH, covered under OSHA Hazard Communication Standard
Labeling Requirements: GHS labeling required, hazard pictograms, risk and safety phrases printed on containers
Restrictions: Use only as authorized for industrial purposes, observe conditions set by environmental agencies
