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Sandranol — Material Safety Data Sheet (MSDS)

Identification

Product Name: Sandranol
Chemical Name: 3,7-Dimethyl-2,6-octadien-1-ol, synthetic
CAS Number: 87-55-7
Molecular Formula: C10H18O
Synonyms: Sandalwood alcohol, alpha-Santalol
Recommended Use: Fragrance component, cosmetic ingredient
Supplier: Commonly provided by fragrance and chemical suppliers
Emergency Contact Number: Refer to supplier data sheet or local emergency directory

Hazard Identification

Classification: Eye irritant, skin sensitizer, harmful if swallowed
Label Elements: Harmful symbol, irritant symbol
GHS Hazard Statements: Causes skin irritation, may cause allergic skin reaction, causes serious eye irritation
GHS Precautionary Statements: Wash hands thoroughly after handling, avoid breathing vapors, wear protective gloves and eye protection, in case of contact with eyes rinse cautiously
Routes of Exposure: Inhalation, skin, eyes, ingestion
Main Hazards: Can irritate skin and eyes, triggers allergies in susceptible persons, mild central nervous system effects if ingested

Composition / Information on Ingredients

Main Ingredient: Sandranol 95–100%
Impurities: May contain small amounts of related terpenoid alcohols
Other Components: Unknown trace substances possible, not expected to alter hazard profile
Purity: Industrial grade or fragrance grade, check supplier specification

First Aid Measures

Inhalation: Move person to fresh air, keep comfortable, seek medical attention if symptoms persist
Skin Contact: Remove contaminated clothing, wash skin with plenty of soap and water, seek medical help with ongoing irritation
Eye Contact: Rinse cautiously with clean water for several minutes, remove contact lenses, continue rinsing, get medical attention for continued discomfort
Ingestion: Rinse mouth, do not induce vomiting, get medical assistance if feeling unwell
Most Important Symptoms: Redness, itching, burning sensations, respiratory tract discomfort, headache in case of large spill fumes

Fire-Fighting Measures

Suitable Extinguishing Media: Foam, dry powder, CO2, water spray (not full water jet)
Unsuitable Extinguishing Media: Strong water jets risk spreading and splattering liquid
Specific Hazards: Vapors may form explosive air-vapor mixtures, combustion produces toxic fumes (carbon monoxide, oxides of carbon)
Protective Equipment: Self-contained breathing apparatus, full protective clothing
Fire/Explosion Risk: Containers exposed to fire may burst, runoff may pollute watershed
Firefighting Instructions: Isolate scene, cool containers with water spray, prevent fire-fighting run-off from entering drains or watercourses

Accidental Release Measures

Personal Precautions: Evacuate area, avoid contact with skin and eyes, use appropriate protective equipment
Environmental Precautions: Contain spill to prevent entry into drains or soil
Methods for Clean-Up: Absorb with inert material (sand, earth), collect for disposal in labeled containers, ventilate area
Handling of Waste: Dispose of clean-up materials as hazardous waste, follow national and local regulations

Handling and Storage

Handling: Use in ventilated area, do not eat, drink, or smoke during handling, minimize all unnecessary exposure
Storage Conditions: Store in tightly-sealed original container, in cool, dry, well-ventilated location, away from sources of ignition
Incompatible Materials: Strong oxidizers, acids, bases
Other Storage Guidance: Protect from sunlight, keep away from food and drink, keep out of reach of children

Exposure Controls and Personal Protection

Exposure Limits: No established occupational exposure limits for Sandranol
Engineering Controls: Use local exhaust ventilation, ensure adequate general ventilation
Personal Protective Equipment:
Eye Protection: Safety goggles or face shield
Skin Protection: Protective gloves, long-sleeved clothing
Respiratory Protection: Respirator with organic vapor cartridge if level exceeds recommendations, especially in case of spill or poorly ventilated areas
Hygiene Measures: Wash hands before breaks and after use, remove contaminated clothing/gear before eating

Physical and Chemical Properties

Physical State: Clear to pale yellow liquid
Odor: Woody, sandalwood-like fragrance
Odor Threshold: Detectable at low concentrations, approximately 0.03 ppm
pH: Not measured (insoluble in water)
Melting Point: -20° to -10°C
Boiling Point: Approx. 250–258°C
Flash Point: 95°C (closed cup)
Evaporation Rate: Low, slower than n-butyl acetate
Flammability: Not highly flammable, but burns in fire
Vapor Pressure: 0.01 mmHg at 25°C
Vapor Density: 5.35 (air = 1)
Relative Density: 0.95–0.97 g/cm3 at 20°C
Solubility: Insoluble in water, soluble in ethanol, oils
Partition Coefficient (n-octanol/water): logP around 3.5
Autoignition Temperature: 265°C
Decomposition Temperature: Above 250°C
Viscosity: Medium, syrupy liquid

Stability and Reactivity

Chemical Stability: Stable under normal conditions, poorly stable under direct sunlight, air, strong oxidizers
Hazardous Reactions: Avoid contact with strong acids, bases, strong oxidizers
Conditions to Avoid: High heat, open flame, prolonged storage with air
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, aromatic hydrocarbons on combustion
Polymerization: Not known to occur under normal use

Toxicological Information

Acute Toxicity: Low toxicity by oral, dermal, inhalation routes
LD50 (oral, rat): Estimated over 2,000 mg/kg
LD50 (dermal, rabbit): Over 2,000 mg/kg
Skin Irritation: Causes irritation on prolonged contact
Eye Irritation: Moderate, leads to redness and pain
Respiratory Sensitization: May provoke coughing, mild congestion in sensitive individuals
Skin Sensitization: Risk of allergic response in predisposed persons
Chronic Toxicity: Repeat exposure may lead to dermatitis
Carcinogenicity: Not classified as carcinogen by IARC, ACGIH, NTP, or OSHA
Mutagenicity/Reproductive Toxicity: No evidence for mutagenic or reproductive effects

Ecological Information

Ecotoxicity: Harmful to aquatic life with long lasting effects
Persistence and Degradability: Partly biodegradable, persistence possible in soil or water
Bioaccumulative Potential: Potential for moderate bioaccumulation (logP > 3)
Mobility in Soil: Low water solubility, likely to adsorb to soil particles
Other Adverse Effects: Not classified as very toxic, but releases in large quantities could disrupt aquatic ecosystems

Disposal Considerations

Disposal Methods: Incinerate in authorized facility or dispose of as chemical waste according to local, regional, national regulations
Contaminated Packaging: Clean containers before recycling, otherwise dispose as hazardous waste
Special Precautions: Do not release into environment, avoid contamination of water sources, landfill only if incineration or other means unavailable

Transport Information

UN Number: Not regulated as dangerous goods for most shipping modes
Proper Shipping Name: Chemical, N.O.S. (Sandranol)
Transport Hazard Class: Not classified
Packing Group: Not assigned
Marine Pollutant: Not classified, avoid bulk spills into waterways
Special Precautions for Transport: Secure tightly, keep upright, prevent leaks or spillage, transport with compatible materials only

Regulatory Information

Labeling Requirements: GHS-compliant warning for skin/eye irritation and sensitization
Chemical Inventory Status: Listed in TSCA (US), EINECS (EU), DSL (Canada) inventories
EPA, OSHA, REACH Regulations: Subject to general chemical safety controls, not subject to specific restriction, but must follow GHS labeling and worker safety provisions
Other National Regulations: Workers exposed in occupational settings fall under general hygienic and safety legislation
Community Guidelines: Use must comply with IFRA (International Fragrance Association) guidelines for fragrance safety